Your product category pages should only focus on 1 or 2 keywords. If you come out with a lot of keywords on one page, it may look like you are keyword stuffing. The only way to tell which are going to be your best keywords is by hooking up Google Analytics and setting up conversion goals. This will tell you he value of the keyword. If you are using Google adwords, it'll tell you if a particular keyword is making or losing you money.
I always break things down into categories.
Mens shirt, Womens shirt, Baby Shirt, Dog shirt. You won't run into so much duplication like you would with the two categories you are talking about (baby & shirt). Use the Control F in Excel to find and replace duplicate keywords.