As tom says 404 errors are not the end of the world.
if you are concerned then as long as the relative urls have remained the same and the root directory is all that has changes a 301 in bulk should work, though if you've changed categories or something it may not work so well as a single entity and 100 would be the way to go.
Something that you should do, if you've not already, is within webmaster tools make sure you tell Google you've changed your url (configuration > change address) - it also has a mini guide on the steps you should be taking, including to register your new domain on webmaster tools.
But again, as tom says, if it's not destroying the user experience and isn't a huge annoyance for visitors don't worry too much about it.
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Just for your reference a full url redirect (aka changing say abc.com to abc.net - moving all directories and urls in one go) would look like
RedirectMatch 301 ^(.*)$ http://www.abc.net
