Ah, WordPress. Yes, all of your duplicate title tag and duplicate content warnings are probably caused by the way that WordPress handles archives out of the box. WordPress has all of your tag archive pages, category pages, author archives, etc. set to Index. So this means one post is duplicated in a potentially infinite amount of places (depending on the number of tags on it) and every page2/page3/page4 winds up duplicating the title tag.
What works well for many is picking up a plugin like Yoast; changing the post preview setting to the snippet instead of full (That way you don't have the full post appearing on every page, only a blurb until you click through to the page where the post actually sits); set Tag Archives, Author Archives, and potentially Category Archives to NoIndex,Follow; and look into cleaning up any useless One-Off tags.
As for what Canonicalization is... in simple terms its like a redirect except for bots only. The tag lets the search engines know that you feel a page is a duplicate or a subset of another page and would like them original canon page to rank in its place and they redirect equity towards that place while leaving the page intact, visible and accessible to the general populace.