Quite the reverse, I would say not to do so. There is certainly no benifit to you, and in the case the algo decided your no-follow link was the more relivent one you would lose all the potential link power for that page to the other page.
No-Follow is supposed to be used only for links to sites you do not wish to be assossiated with, and paid links. Using it for internal navigation isn't something that has been common since page rank sculpting stoped working.