Thank you for the link, but I'm still unsure about these two specific issues.
Issue One:
So I have say the two below links, which are the same category but just page 1 and 2.
Page 1: http://www.interstellarstore.com/star-wars-memorabilia
Page 2: http://www.interstellarstore.com/star-wars-memorabilia/page/2/
Should Page 1 be the Canonical for all subsequent pages, or by their own rights is Page 2 and onward considered their own page? From what I understand of the former this would cause a Duplicate Title problem. The latter however would surely cause problems for Google as it would ignore all of the products on Pages 2 and onward?
Currently I have Rel Canonical and Rel Prev/Next in place, am I correct in thinking this is the correct way to do this?
Issue Two:
One of the below links is the main category (Canonical) while the other is indirect from the Brand option available on our site.
Category: http://www.interstellarstore.com/star-wars-memorabilia
Brand: http://www.interstellarstore.com/star-wars-memorabilia?page=2%2F
Am I correct in thinking that the Canonical URL displayed on the Brand page should in fact be the Category URL above?
I'm sorry for all the questions, I'm just trying to make heads to tails of the issue. Currently there are over 20,000 Duplicate Title issues and I'm thinking this may be the cause.