Thank you Cyrus I will certainly read the blog post and consider the noindex, nofollow on content with a canonical tag that differs from the current served page' uri.
I am still at little confused as to why the SEOMOZ crawl is highlighting duplicate pages when the canonical tag is present and pointing to the primary content.
Take the following example page for example:-
http://www.planksclothing.com/planks-classic-t-shirt-black-multi.html
Firstly the page has a canonical tag. There is no search on the site and product is viewed a root level without directory structure, which in a Magento instance is the common problem with duplicate content...
Currently at the time of writing SEOMOZ is updating my duplicate repor, so I can't find out what is the duplicate content. Maybe it is updating to say it is not 
Thanks
Amendment: After reading the supplied blog post (http://www.seomoz.org/blog/duplicate-content-in-a-post-panda-world) I have learn't that the above page is just not different and probably is in the area of "Thin Content".