Questions
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301 Redirects Relating to Your XML Sitemap
I think that - adding the new URL while keeping the old ones in XML sitemap for a bit - is your best idea. You can manually add your new URL to index using GWT tools, as well, but I think it's best practice to wait for your site to be crawled again before removing old links from XML sitemap.
Technical SEO Issues | | BradyDCallahan0