Hi Ben,
You probably want to redirect a single page if it is going to a 404. In which case you probably just want add code into the header of the problem page. Whilst you are at it, it might be worth checking that your non-www. pages are forwarding to the www versions. (http://exampledomain.com -> http://www.exampledomain.com)
PHP Redirect
Header( "HTTP/1.1 301 Moved Permanently" );
Header( "Location: http://www.exampledomain.com" );
?>
Htaccess 301 Redirect (non-www. to www.)
Options +FollowSymLinks RewriteEngine On
RewriteBase / RewriteCond %{HTTP_HOST} !^www.exampledomain.com$ [NC] RewriteRule ^(.*)$ http://www.exampledomain.com/$1 [R=301,L]
Custom 404 Page
I would also suggest a custom 404 page with links to your most popular pages, search and a back button.
Hope this helps.
C